Improved dye-sensitized solar cell with a ZnO nanotree photoanode by hydrothermal method
نویسندگان
چکیده
This study investigated the influence of ZnO nanostructures on dye adsorption to increase the photovoltaic conversion efficiency of solar cells. ZnO nanostructures were grown in both tree-like and nanorod (NR) arrays on an AZO/FTO film structure by using a hydrothermal method. The results were observed in detail using X-ray diffraction, field-emission scanning electron microscopy (FE-SEM), UV-visible spectrophotometry, electrochemical impedance spectroscopy, and solar simulation. The selective growth of tree-like ZnO was found to exhibit higher dye adsorption loading and conversion efficiency than ZnO NRs. The multiple 'branches' of 'tree-like nanostructures' increases the surface area for higher light harvesting and dye loading while reducing charge recombination. These improvements result in a 15% enhancement in power conversion. The objective of this study is to facilitate the development of a ZnO-based dye-sensitized solar cell.
منابع مشابه
Fabrication of dye sensitized solar cells with a double layer photoanode
Dye sensitized solar cell was fabricated from a double layer photoanode. First, TiO2 nanoparticles were synthesized by hydrothermal method. These TiO2 NPs were deposited on FTO glasses by electrophoretic deposition method in applied voltage of 5 V and EPD time of 2.5-10 min. Then TiO2 hollow spheres (HSs) were synthesized by sacrificed template method with Carbon Spheres as template and TTIP ...
متن کاملInfluence of TiO2 layer thickness as photoanode in Dye Sensitized Solar Cells
Dye-sensitized solar cells (DSSCs) are categorized as some of inexpensive thin-film solar cells. The basis and foundation of these cells is a semiconductor that consists of an electrolyte and a light-sensitive anode. Titanium dioxide (TiO2) is a semiconductor that plays the role of anode and is the main constituent of these cells. In this paper, we have addressed the functionality and performan...
متن کاملDual-functional ZnO nanorod aggregates as scattering layer in the photoanode for dye-sensitized solar cells.
A bilayered ZnO photoanode was constructed for dye-sensitized solar cells with a high conversion efficiency of 4.0%. One layer made of ZnO nanocrystallites increases dye adsorption, and the other consisting of ZnO nanorod aggregates provides a directed electron pathway for the electron transport together with a prominent aggregation-induced light scattering.
متن کاملThe investigation on different light harvesting layers and their sufficient effect on the photovoltaic characteristics in dye sensitized solar cell
Titanium dioxide-based nanofibers (TiO2 nanofiber) were prepared by an electrospinning technique. The electrospun composite fibers were synthesized at different concentrations of titanium isopropoxide (25.35, 50.69, 76.05 wt%) and calcinated at different temperatures (450 oC, 650 oC and 850 oC) for 2 h. The diameters of nanofibers decreased by increas...
متن کاملElectric-Field-Assisted Growth of Ga-Doped ZnO Nanorods Arrays for Dye-Sensitized Solar Cells
A photoanode with Ga-doped ZnO nanorods has been prepared on F-doped SnO2 (FTO) coated glass substrate and its application in dye-sensitized solar cells (DSSCs) has been investigated. Gadoped ZnO nanorods have been synthesized by an electric-field-assisted wet chemical approach at 80 ̊C. Under a direct current electric field, the nanorods predominantly grow on cathodes. The results of the X-ray ...
متن کامل